The artist has had solo exhibitions at Library Street Collective, Detroit, USA; Pearl Lam Galleries, Hong Kong, China; Dallas Contemporary, Texas, USA; Bass Museum of Art, Miami, USA; Baltic Centre for Contemporary Art, Gateshead, UK; Museo de Arte de Puerto Rico, San Juan, Puerto Rico, USA; and CAM Contemporary Art Museum, St. Louis, Missouri, USA. His work has also been exhibited in group shows at The FLAG Art Foundation, New York, USA; Daegu Art Museum, Korea; The Museum of Contemporary Art, Chicago, USA; Marta Herford Museum, Herford, Germany; Museum Het Domein, Sittard, the Netherlands; Museum of Contemporary Art, San Diego, USA; Museo del Barrio, New York, USA; and Centro Atlántico de Arte Moderno (CAAM), Canary Islands. In 2007, Rolón’s work was featured in the Ukraine Pavilion at the 52nd Venice Biennale. He is a recipient of the Joan Mitchell Foundation Award for Painting and Sculpture.

Rolón’s work can be found in many public collections, including Bass Museum of Art, Miami, USA; Brooklyn Museum, New York, USA; City of Chicago Public Art Collection, Illinois, USA; Museo del Barrio, New York, USA; Museo de Arte de Puerto Rico, San Juan, Puerto Rico, USA; Museum Het Domein, Sittard, the Netherlands; Museum of Contemporary Art, San Diego, USA; Nerman Museum of Contemporary Art, Overland Park, Kansas; and Pinchuk Art Centre, Kiev, Ukraine.